ORIGINAL RESEARCH ARTICLE Green synthesis of TiO2particles using lime juice/lime Peel extract: photo degradation of dye in water

Khadijat O. Abdulwahab(1), Ajibola M. Ayorinde(2), Luqmon K. Adams(3),


(1) University of Lagos
(2) University of Lagos
(3) University of Lagos
Corresponding Author

Abstract


In this work, titanium dioxide (TiO2) particles were synthesized from bulk Titania using lime juice or lime peel as capping agents. The synthesized TiO2 nanoparticles were characterized using powder X-Ray Diffraction (p-XRD), Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS) and Ultra-Violet Spectroscopy (UV-VIS). The photocatalytic property of the titania nanoparticles was tested by applying these nanoparticles to degrade methylene blue dye solution. The p-XRD pattern revealed an anatase structure. The SEM results showed that the nanoparticles capped with the lime peel extract had better shape and size distribution than those obtained from lime juice. This is quite interesting as the peel which would have been ordinarily considered a waste was found to be useful. The degradation of methylene blue showed that the titania nanoparticles could be applied to degradation of dye contaminated water. This process is simple, non-toxic, inexpensive and can be used for the remediation of effluents from dye and textile industries before they are discharged into the ocean. This in turn will keep the ocean clean and preserve the aquatic life.

Keywords


Titanium dioxide nanocubes, Green synthesis, Dye Degradation

References


Abdul Jalill R D H., Nuaman R S, & Abd A N (2016). Biological synthesis of Titanium Dioxide nanoparticles by Curcuma longa plant extract and study its biological properties. World Scientific News. 49: 204-22

Baker S, Rakshith D, Kavitha K S, Santosh P, Kavitha H U, Rao Y, & Satish S (2013). Plants: Emerging as nanofactories towards facile route in synthesis of nanoparticles. BioImpacts. 3: 111-117

Barkul R P, Patil M.K, Patil S M, Shevale V B, & Delekar S D (2017) Sunlight-assisted photocatalytic degradation of textile effluent and Rhodamine B by using iodine doped TiO2 nanoparticles. Journal of Photochemistry and Photobiology A: Chemistry. 349: 138-147.

Chatterjee A, Nishanthini D, Sandhiya N, & Jayanthi A (2016). Biosynthesis of Titanium Dioxide Nanoparticles Using Vigna Radiata. Asian journal of pharmaceutical and clinical research.9: 85-88.

Chen X, & Mao S (2007). Titanium Dioxide Nanomaterials: Synthesis, Properties, Modifications, and Applications. Chemical Review. 107: 2891-2959.

Dobrucka R (2017). Synthesis of Titanium Dioxide Nanoparticles Using Echinacea purpurea Herba Iranian Journal of Pharmaceutical Research.16:756-762.

Hariharan D, Srinivasan K, & Nehru L C (2017). Synthesis of TiO2 nanoparticles using Cynodon Dactylon leaf extract for Antibacterial and Anticancer (A549 Cell Lines) Activity. Journal of Nanomedicine Research. 5: 1-5.

Jafari S, Mahyad B, Hashemzadeh H, Janfaza S, Gholikhani T, & Tayebi L (2020). Biomedical Applications of TiO2 Nanostructures: Recent Advances. International Journal of Nanomedicine. 15: 3447-3470.

Konstantinou I K & Albanis T A (2004). TiO2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations: a review. Applied Catalysis B: Environmental. 49: 1–14.

Natarajan K, Bajaj H C, & Tayade R J (2018) Effective removal of organic pollutants using GeO2/TiO2 nanoparticle composites under direct sunlight. Materials Chemistry Frontiers, 2: 741-751.

Nicolás A O, Luis A S, Vicente MD, Denisse M B, & José MP (2014). Use of titanium dioxide nanoparticles biosynthesized by Bacillus mycoides in quantum dot sensitized solar cells. Microbial Cell Factories. 13: 1-10.

Prasad R (2014). Synthesis of Silver Nanoparticles in Photosynthetic Plants. Journal of Nanoparticles. 2014: 1-9.

Raliya R, Avery C, Chakrabarti S, & Biswas P (2017). Photocatalytic degradation of methyl orange dye by pristine titanium dioxide, zinc oxide, and graphene oxide nanostructures and their composites under visible light irradiation. Applied Nanoscience. 7: 253-259.

Rao K G, Ashok C H, Rao K V, Chakra C H S, & Rajendar V (2015). Synthesis of TiO2 Nanoparticles from Orange Fruit Waste. Synthesis. 2: 82-90.

Strambeanu N, Demetrovici L, & Dragos D (2015) in Natural Sources of Nanoparticles. (Springer International Publishing Switzerland), pp9-19.

Sundrarajan M, & Gowri S (2011) Green Synthesis of Titanium Dioxide Nanoparticles by Nyctanthes Arbortristis Leaves Extract. Chalcogenide Letters. 8:447-451.

Zhao J, Wu T, Wu K, Oikawa K, Hidaka H, & Serpone, N (1998). Photoassisted Degradation of Dye Pollutants. 3. Degradation of the Cationic Dye Rhodamine B in Aqueous Anionic Surfactant/TiO2 Dispersions under Visible Light Irradiation: Evidence for the Need of Substrate Adsorption on TiO2 Particles. Environmental Science Technology. 32:2394-2400.


Full Text: PDF

Article Metrics

Abstract View : 260 times
PDF Download : 97 times

DOI: 10.57046/KCRN9556

Refbacks

  • There are currently no refbacks.


Copyright (c) 2021 Proceedings of the Nigerian Academy of Science

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.