Metals contamination of Aquifer in Warri and Port- Harcourt (Niger – Delta Region)
(1) Bioresources Development Centre, National Biotechnology Development Agency .Ogbomoso
(2) Bioresources Development Centre, National Biotechnology Development Agency .Ogbomoso
(3) Bioresources Development Centre, National Biotechnology Development Agency .Ogbomoso
(4) Bioresources Development Centre, National Biotechnology Development Agency .Ogbomoso
(5) Bioresources Development Centre, National Biotechnology Development Agency .Ogbomoso
Corresponding Author
Abstract
Heavy metal concentrations of hand-dug wells from twelve (12) locations within Warri and Port Harcourt metropolis of (Niger - Delta region) were studied. Twenty – four (24) hand-dug well water samples were analysed. The physicochemical parameters of the water samples were analyzed using Standard methods within 24 hours. The metal cations were also determined using Atomic Absorption Spectrophotometer (AAS) method, hardness, chloride and bicarbonate concentrations were determined using titrimetric method, sulphate was determined by spectrophotometer method. Most physicochemical parameters were found to be within the WHO acceptable limits for drinking water in all sample locations. Rumagbo and Udu has the highest (108.5 and 288.55 mg/L) while Elewere and Enware lowest (36.08 and 36.05 mg/L) concentrations of bicarbonate (HCO3-) respectively, the highest concentration of sulphate (SO42-) was recorded in Waterline and Efurun (72.00 and 82.75 mg/L). chloride (Cl-) (96.75 and 107.25 mg/L) for Mgbuoba and NPA meanwhile nitate (NO3-) (0.05 and 0.06 mg/L) have their highest concentrations observed at Eligbolo and NPA respectively. Eligbolo, and Udu have the highest concentration of manganese (Mn). Meanwhile arsenic (As) concentration was found to be highest in Rumuola and Udu (0.75 and 0.77mg/L) with the lowest concentration found in Elewere and Enware (0.38 and 0.46mg/L) respectively. In all, the concentrations of metals from the water samples observed were above the WHO limits of heavy water concentrations in drinking water. The results from this study show that there is high level of contamination of the aquifer (groundwater) in the studied areas. The long-term effect of continuous consumption of this groundwater can be of pose a threat to the health of the people.
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References
Abbas G, Murtaza B, Bibi I, Shahid M, Niazi NK, Khan MI, Amjad M, Hussain M, Natasha (2018). Arsenic uptake, toxicity, detoxification, and speciation in plants: physiological, biochemical, and molecular aspects. Int J Environ Res Public Health 15:59. https :// doi.org/10.3390/ijerp h1501 0059.
Abdulhadi B.A., Kot P., Hashim K.S., Shaw A., Khaddar R.A.( 2019). Influence of current density and electrodes spacing on reactive red 120 dye removal from dyed water using electrocoagulation/electroflotation (EC/EF) process; Proceedings of the First International Conference on Civil and Environmental Engineering Technologies (ICCEET); Najaf, Iraq. pp. 12–22.
Adepoju-Bello, A. A., Ojomolade O. O., Ayoola G. A., and Coker H. A. B (2009). Quantitative analysis of some toxic metals in domestic water obtained from Lagos metropolis. The Nig. J. Pharm.; 42 (1):57-60
Adepoju-Bello, A.A. and Alabi, O.M. 2005. Heavy metals: A review. The Nig. J. Pharm., 37: 41-45.
Adeyemi, O.,O.B. Oloyede and A.T. Oladiji, (2007). Physicochemical and microbial characteristics of Leachate contaminated ground water. Asian J. Biochem., 2(5): 343-348.
Adeyeye, E. I. (2000).. “Bio-concentration of macro and trace elements in prawns living in Lagos Lagoon”. Pakistan Journal of Scientific and Industrial Research, 43:367 – 373.
Ahaneku I.E, and Adeoye P.A (2014) Impact of pit latrines on groundwater quality of Fokoslum, Ibadan, Southwestern Nigeria. Brit J of Appl Sci and Tech 4(3):440–449
Balasubramanian D.N. In: The Hydrologic Cycle. Mysore U.O., editor. Centre for Advanced Studies in Earth Science, University of Mysore; Karnataka, India: 2017. p. 1.
Basu A, Saha D, Saha R, Ghosh T, Saha B (2014) A review on sources, toxicity and remediation technologies for removing arsenic from drinking water. Res Chem Intermediation 40:447–485
D. H. Hardy, J. Myers and C. Stokes, (2008). Heavy Metals in North Carolina Soils, Occurrence & Significance, N.C: Department of Agriculture and Consumer Services, pp. 1-2.
Ebong G. A and Etuk, H.S. (2017). Potability of Groundwater in Itu Local Government Area, South-South of Nigeria. International Journal of Materials Science and Applications. 6, (3):pp. 126-135
Elumalai V, Nethononda VG, Manivannan V, Rajmohan N, Li P, Elango L (2020) Groundwater quality assessment and application of multivariate statistical analysis in Luvuvhu catchment, Limpopo, South Africa. J Afr Earth Sci 171:103967. https ://doi. org/10.1016/j.jafre arsci .2020.10396 7
FGN (Federal Government of Nigeria). (2012.). A report of water resources in Nigeria in the world water day. The Nation Newspaper, Abuja. Ferrier, C. 2001. Bottled water. Understanding a social phenomenon. Journal of Human Environment, 30 (2): 15 – 24.
Goldhaber MB, Mills CT, Morrison JM, Stricker CA, Mushet DM, LaBaugh JW (2014) Hydrogeochemistry of prairie pothole region wetlands: role of long-term critical zone processes. Chem Geol 387:170–183. https ://doi.org/10.1016/j.chemg eo.2014.08.023
Government of Canada (2017). Groundwater contamination. https :// www.canad a.ca/en/envir onmen t-clima te-chang e/servi ces/water -overv iew/pollu tion-cause s-effec ts/groun dwate r-conta minat ion. html. Accessed 17 Oct 2020
Grönwall J., Danert K.( 2020;) Regarding Groundwater and Drinking Water Access through A Human Rights Lens: Self-Supply as A Norm. Water. 12:419. doi: 10.3390/w12020419.
Hansen B, Thorling L, Schullehner J, Termansen M, Dalgaard T (2017) Groundwater nitrate response to sustainable nitrogen management. Sci Rep 7:8566. https ://doi.org/10.1038/s4159 8-017-07147 -2
Hashim MA, Mukhopadhyay S, Sahu JN, Sengupta B (2011) Remediation technologies for heavy metal contaminated groundwater. J Environ Manag 92:2355–2388
Hassan W., Faisal A., Abed E., Al-Ansari N., Saleh B. New Composite Sorbent for Removal of Sulfate Ions from Simulated and Real Groundwater in the Batch and Continuous Tests. Molecules. 2021; 26:4356. doi: 10.3390/molecules26144356. [PMC free article] [PubMed]
He S, Wu J (2019) Hydrogeochemical characteristics, groundwater quality and health risks from hexavalent chromium and nitrate in groundwater of Huanhe Formation in Wuqi County, northwest China. Expo Health 11:125–137
He X, Li P, Wu J, Wei M, Ren X, Wang D (2020a) Poor groundwater quality and high potential health risks in the Datong Basin, northern China: research from published data. Environ Geochem Health. https ://doi.org/10.1007/s1065 3-020-00520 -7
He X, Wu J, He S (2019) Hydrochemical characteristics and quality evaluation of groundwater in terms of health risks in Luohe aquifer in Wuqi County of the Chinese Loess Plateau, northwest China. Hum Ecol Risk Assess 25:32–51
Hvitved-Jacobson, T. and Y. A. Yousef.( 1991). Highways run off quality, environmental impacts and Control. In Highway Pollution, Elsevier. London. pp. 165 – 208.
Igwilo, I.O., Afonne, O.J. Maduabuchi, U.J. and Orisakwe, O.E. 2006. Toxicological study of the Anam River in Otuocha, Anambra State, Nigeria. Arch. Environ. Occup. Health, 61(5): 205-208.
Ikem, A.; S. Odueyungbo; N. O. Egiebor and K. Nyavor. (2002).. “Chemical quality of bottled water from three cities in Eastern Alabama”. The Science of the Total Environment, 285: 165 – 175.
International Association of Hydrogeologists (2020) Groundwater— more about the hidden resource.https://iah.org/education/gener alpublic/groundwater-hidden-resource. Accessed 13 Nov 2020
Karunanidhi D, Aravinthasamy P, Subramani T, Wu J, Srinivasamoorthy K (2019) Potential health risk assessment for fluoride and nitrate contamination in hard rock aquifers of Shanmuganadhi River basin, South India. Hum Ecol Risk Assess 25:250–270
Lawal R. A and Lohdip Y.N (2011). Physicochemical and microbial analysis of water from Mimyak River in Kanke LGA of Plateau state, Nigeria. Afr. J. Nat. Sci.14:5-7.
Li P (2020) To make the water safer. Expo Health 12:337–342
Li P, He X, Guo W (2019a) Spatial groundwater quality and potential health risks due to nitrate ingestion through drinking water: a case study in Yan’an City on the Loess Plateau of northwest China. Hum Ecol Risk Assess 25:11–31
Li P, Wu J (2019) Sustainable living with risks: meeting the challenges. Hum Ecol Risk Assess 25:1–10
Li P, Wu J, Qian H (2016) Preliminary assessment of hydraulic connectivity between river water and shallow groundwater and estimation of their transfer rate during dry season in the Shidi River, China. Environ Earth Sci 75:99. https ://doi.org/10.1007/s1266 5-015-4949-7
Li P, Wu J, Tian R, He S, He X, Xue C, Zhang K (2018) Geochemistry, hydraulic connectivity and quality appraisal of multilayered groundwater in the Hongdunzi coal mine, northwest China. Mine Water Environ 37:222–237
Lin H (2010) Earth’s critical zone and hydropedology: concepts, characteristics, and advances. Hydrol Earth Syst Sci 14:25–45
M.A.Momodu andC.A Anyakora (2010). Heavy Metal Contamination of Ground Water: The Surulere Case Study. Res. J. Environ. Earth Sci., vol. 2(1), pp. 39-43.
Majuru B, Michael MM, Jagals P, Hunter PR (2011) Health impact of small-community water supply reliability. Internl J Hygi Environl Health 214(2):162–166
Marcovecchio J. E., Botte S. E. and Freije R. H. (2007). Heavy Metals, Major Metals, Trace Elements. In: Handbook of Water Analysis. L.M. Nollet, (Ed.). 2nd Edn. London: CRC Press; pp. 275-311.
Megdal S.B. Invisible water: The importance of good groundwater governance and management. NPJ Clean Water. 2018; 1:15. doi: 10.1038/s41545-018-0015-9
Monday .E. Ossai, Ibrahim O. Bazambo, Titilola T. Falese, Nurein O. Falade and ,Adekunle A. Adefemiwa.( 2021). Assessment of groundwater contamination in Port-Harcourt areas. International Journal of Scientific Research and Engineering Development-– Volume 4 Issue 2, 219 – 228.
NIS (Nigerian Industrial Standard) (2007). Nigerian Standard for Drinking Water Quality. Available at: http://www.unicef.org/nigeria/ng_publications_Nigerian_Standard_for_Drinking_Water_Quality.pdf Accessed 02 Nov 2016
Obaroh I.O, Abubakar U, Haruna M.A and Elinge M.C (2015). Evaluation of some heavy metals concentration in River Argungu. J. Fish. Aquat. Sci. 10(6):581-586.
Ohwoghere AO (2012) Heavy metals distribution in degraded land forms in Delta State of the Niger Delta. J Geolgy Min Res 4(3):43–50
Omran I.I., Al-Saati N.H., Hashim K.S., Al-Saati Z.N., Patryk K., Khaddar R.A., Al-Jumeily D., Shaw A., Ruddock F., Aljefery M.( 2019). Assessment of heavy metal pollution in the Great Al-Mussaib irrigation channel. Desalination Water Treat.;168: 165–174. doi: 10.5004/dwt.2019.24600.
Pandey HK, Duggal SK, Jamatia A (2016) Fluoride contamination of groundwater and its hydrological evolution in District Sonbhadra (U.P.) India. Proc Nat Acad Sci India Sect A Phys Sci 86:81–93
Rebelo FM, Caldas ED, (2016). Arsenic, lead, mercury and cadmium: toxicity, levels in breast milk and the risks for breastfed infants. Environ Res 51:671–688
Ryecroft S.P., Shaw A., Fergus P., Kot P., Hashim K., Conway L. A Novel Gesomin Detection Method Based on Microwave Spectroscopy; Proceedings of the 12th International Conference on Developments in eSystems Engineering (DeSE); Kazan, Russia. 7–10 October 2019; pp. 429–433.
Sawyer AH, Michael HA, Schroth AW (2016) From soil to sea: the role of groundwater in coastal critical zone processes. WIREs Water 3:706–726
Serio F, Miglietta PP, Lamastra L, Ficocelli S, Intini F, De Leo F, De Donno A (2018) Groundwater nitrate contamination and agricultural land use: a grey water footprint perspective in Southern Apulia Region (Italy). Sci Total Environ 645:1425–1431
Su Z, Wu J, He X, Elumalai V (2020) Temporal changes of groundwater quality within the groundwater depression cone and prediction of confined groundwater salinity using Grey Markov model in Yinchuan area of northwest China. Expo Health 12:447–468
Subba Rao N, Ravindra B, Wu J (2020) Geochemical and health risk evaluation of fluoride rich groundwater in Sattenapalle Region, Guntur district, Andhra Pradesh, India. Hum Ecol Risk Assess 26:2316–2348.
Taiwo, A.M, Towolawi, A.T, Olanigan, A.A, Olujimi, O.O and Arowolo, T.A. (2015). Comparative Assessment of Groundwater Quality in Rural and Urban Areas of Nigeria. In Research and Practices in Water Quality.
WHO. (2011).“Guidelines for drinking water quality”. World Health Organization, Geneva, Volume 1, 4th Edition.
Wu J, Li P, Qian H (2015) Hydrochemical characterization of drinking groundwater with special reference to fluoride in an arid area of China and the control of aquifer leakage on its concentrations. Environ Earth Sci 73:8575–8588
Wu J, Li P, Qian H, Fang Y (2014) Assessment of soil salinization based on a low-cost method and its influencing factors in a semi-arid agricultural area, northwest China. Environ Earth Sci 71(8):3465–3475. https ://doi.org/10.1007/s1266 5-013-2736-x
Zhang Y, Wu J, Xu B (2018) Human health risk assessment of groundwater nitrogen pollution in Jinghui canal irrigation area of the loess region, northwest China. Environ Earth Sci 77:273
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DOI: 10.57046/KKAG8067
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